Magadh University PhD Entrance Chemistry Syllabus / PhD Admission Test Chemistry Syllabus: Magadh University PhD Admission Test (PAT) Chemistry Syllabus are written here. Its Syllabus is in PDF Format. All Students who want to Appeare in this PhD Entrance Test can check their PhD Entrance Chemistry Syllabus from here in free.

Magadh University PhD Entrance Chemistry Syllabus

Time: 2 Hours

Full Marks: 100 Marks

There will be two papers of 100 marks each. Paper I will be aimed at testing general awareness of the candidate in Chemistry. In this paper there will be 50 questions of objective type carrying 2 marks each. The candidate will be required to attempt all questions in this paper in 3 hours.

Atomic Structure and Bonding:

Photoelectric effect, H. Spectra, Bohr model Vector model of atoms. Concept of angular momentum an electron, quantum numbers, Schrodinger equatio Eigen function and Eigen values, shapes of orbitals, radi and angular probability curves. Uncertainty principl Hund’s rules, Aufbau principle, Pauli’s exclusion principl Electronic configuration of atoms, Term symbols (Grou State), L.S. coupling, jj coupling schemes.

Hybridization, VSEPR theory shapes of simp molecules with and without lone pairs. General features V.B. theory, Variation principle, H2 molecule, Resonanc M.O. theory, treatments of simple homonuclear ar heteronuclear diatomic molecules Born – Haber Cycl Lattice Energy, Band theory, Crystal defects.

Thermodynamics:

Concepts of thermodynamic quantities a functions, free energy & entropy calculations, Carnot cyc Gibb’s Helmholtz eqn, Clausuis-Claperon eqn., Maxw equations, chemical potential, van’t Hoff inotherm a isochore, Nernst Heat theorem and its application to so systems, Third law of thermodynamics.

Chemical Kinetics:

Rate of reaction, factors influencing the rate of a reaction-concentration, T.P. Solvent, light, catalyst. Concentration dependence of rates, mathematical characteristics of simple chemical reactions-zero order, first order, second order, pseudo order, half life and mean ife period. Determination of order of reaction-differential method, method of integration, method of half life period and isolation method. Arrhenius eqn., concept of activation energy. Simple collision theory, expression for rate constant based on equilibrium constant and thermodynamic aspects Catalysis-characteristics, classification, acid-base catalysis, enzyme catalysis.

Electrochemistry:

Conductance- equivalent, specific and molar. elynoo Variations with dilution. Migration of ions, kohlrausch law, Ostwald’s dilution law, limitations. Debye-Huckel-Onsagar eqn, for strong electrolytes (elementary treatment only), Transport no., Hittorf and Moving Boundary Methods, Application of conductivity measurements, measurements of K of acids, determination of solubility product of a sparingly soluble salt. Types of reversible electrodes. Electrode reactions. Nernst equation, Derivation of cell. EMF and single electrode potential, standard electrodes. EMF of a cell. Calculation of AG,A H, K of cell reaction. Over voltage, liquid junction potential. Concentration cells with and without transference.

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