Class 12 Chemistry Ch-9 Coordination Compounds MCQs Exam 2027 New

💁 Ankit Raj

📅 26/02/2026

Class 12 Chemistry Ch-9 Coordination Compounds MCQs Exam 2027

Class 12 Chemistry Ch-9 Coordination Compounds MCQs Exam 2027 MCQs Exam 2027 Details: नीचे दिए गए सभी Questions Bihar Board परीक्षा 2027 के लिए “Very Very Important Multiple Choice Questions (MCQs) Objective” (अत्यंत महत्वपूर्ण प्रश्न) हैं। इन सभी Class 12th Chemistry /रसायन विज्ञानं ) = रसायन विज्ञानं भाग-1 (English Medium) Book Chapter-9 Coordination Compounds का Questions का Solve का वीडियो Youtube और Website पर Upload किया है।

Class 12 Chemistry Ch-9 Coordination Compounds MCQs Exam 2027

Topic 1: Basic Concepts & Double Salts

  1. An example of a neutral ligand is: [BSEB, 2021 A]

    (A) Cyanide group

    (B) Halogen group

    (C) Nitro group

    (D) Water molecule

  2. $K_3[Fe(CN)_6]$ is a/an: [BSEB, 2019 A]

    (A) Double salt

    (B) Coordination compound

    (C) Acidic salt

    (D) Simple compound

  3. Potash alum is an example of: [BSEB, 2011 A]

    (A) Salt

    (B) Simple salt

    (C) Double salt

    (D) Complex salt

  4. The formula of Mohr’s salt is: [BSEB, 2015 A]

    (A) $FeSO_4 \cdot 7H_2O$

    (B) $FeSO_4 \cdot (NH_4)_2SO_4 \cdot 6H_2O$

    (C) $FeSO_4 \cdot (NH_4)_2 SO_4 \cdot 6H_2O$

    (D) $FeSO_4 \cdot 5H_2O$

  5. Which of the following is an example of a double salt? [BSEB, 2023 A]

    (A) Bleaching powder

    (B) $K_4[Fe(CN)_6]$

    (C) Hypo

    (D) Potash alum

  6. The aqueous solution of Potash alum is: [BSEB, 2017 C]

    (A) Acidic in nature

    (B) Basic in nature

    (C) Neutral in nature

    (D) Amphoteric in nature

  7. An example of a double salt is: [BSEB, 2023 A]

    (A) $K_4[Fe(CN)_6]$

    (B) Carnallite ($KCl \cdot MgCl_2 \cdot 6H_2O$)

    (C) $CuSO_4 \cdot 5H_2O$

    (D) $NaCl$

  8. Potassium ferrocyanide is a: [BSEB, 2011 A]

    (A) Simple salt

    (B) Complex salt

    (C) Double salt

    (D) Acidic salt

Topic 2: Classification of Ligands

  1. Ethylenediamine tetraacetate ion ($EDTA^{4-}$) is a: [BSEB, 2022 A]

    (A) Unidentate ligand

    (B) Bidentate ligand

    (C) Hexadentate ligand

    (D) Tridentate ligand

  2. Ethylenediamine is: [BSEB, 2021 A]

    (A) Unidentate ligand

    (B) Bidentate ligand

    (C) Tridentate ligand

    (D) Ambidentate ligand

  3. Which of the following ligands forms a Chelate? [BSEB, 2021 A]

    (A) $Cl^-$

    (B) Oxalate

    (C) $NH_3$

    (D) $CN^-$

  4. All ligands are: [BSEB, 2022 A]

    (A) Lewis acids

    (B) Lewis bases

    (C) Neutral

    (D) None of these

  5. Ligands are capable of donating at least: [BSEB, 2019 C]

    (A) One pair of electrons

    (B) One electron

    (C) Three electrons

    (D) All of these

  6. An example of a positive ligand is: [BSEB, 2011 A]

    (A) $NH_2 – NH_2$

    (B) $NH_2 – NH_3^+$

    (C) $NH_2^-$

    (D) Different from these

  7. Which of the following is a bidentate ligand? [BSEB, 2023 A]

    (A) E.D.T.A.

    (B) Ethylenediamine

    (C) Acetate ion

    (D) Pyridine

  8. An example of the weakest ligand is: [BSEB, 2021 A]

    (A) $Cl^-$

    (B) $OH^-$

    (C) $CN^-$

    (D) $SO_4^{2-}$

  9. Which of the following ligands is unidentate? [BSEB, 2021 A]

    (A) Ethylenediamine

    (B) Oxalate ion

    (C) Ammonia ($NH_3$)

    (D) EDTA

  10. Which of the following is the strongest ligand? [BSEB, 2021 A]

    (A) $F^-$

    (B) $Cl^-$

    (C) $CN^-$

    (D) $OH^-$

  11. An example of an ambidentate ligand is: [BSEB, 2022 A]

    (A) $H_2O$

    (B) $NH_3$

    (C) $SCN^-$

    (D) $C_2O_4^{2-}$

  12. A ligand must have at least how many lone pairs of electrons? [BSEB, 2020 A]

    (A) 1

    (B) 2

    (C) 3

    (D) 4

  13. Which of the following ligands is neutral? [BSEB, 2017 C]

    (A) $CN^-$

    (B) $OH^-$

    (C) $CO$ (Carbonyl)

    (D) $Cl^-$

  14. The denticity of $EDTA^{4-}$ is: [BSEB, 2022 A]

    (A) 2

    (B) 4

    (C) 6

    (D) 1

  15. Ethylenediamine ($en$) is which type of ligand? [BSEB, 2018 A]

    (A) Negative

    (B) Neutral

    (C) Positive

    (D) Acidic

  16. Which of the following ligands forms a chelate ring? [BSEB, 2023 A]

    (A) $NH_3$

    (B) Oxalate

    (C) $H_2O$

    (D) $Cl^-$

Topic 3: Coordination Number & Oxidation State

  1. The oxidation number of Nickel in $[Ni(CO)_4]$ is: [BSEB, 2009 A]

    (A) Zero

    (B) +4

    (C) +2

    (D) -4

  2. The oxidation state of Chromium in $[Cr(CO)_6]$ is: [BSEB, 2021 A]

    (A) +6

    (B) +4

    (C) 0

    (D) +3

  3. The coordination number of $Cr$ in $K_3[Cr(Ox)_3]$ is: [BSEB, 2017 A]

    (A) 6

    (B) 5

    (C) 4

    (D) 3

  4. The oxidation number of Cobalt in $K[Co(CO)_4]$ is: [BSEB, 2021 A]

    (A) +1

    (B) +3

    (C) -1

    (D) -2

  5. The coordination number of $Cr$ in $Na_3[Cr(C_2O_4)_3]$ is: [BSEB, 2020 A]

    (A) 3

    (B) 4

    (C) 5

    (D) 6

  6. The oxidation number of $Cr$ in $[Cr(H_2O)_4Cl_2]^+$ complex is: [BSEB, 2021 A]

    (A) +1

    (B) +3

    (C) +5

    (D) +6

  7. The oxidation number of $Pt$ in $[Pt(C_2H_4)Cl_3]^-$ is: [BSEB, 2023 A]

    (A) +1

    (B) +2

    (C) +3

    (D) +4

  8. The oxidation state of Nickel in $K_4[Ni(CN)_4]$ is: [BSEB, 2021 A]

    (A) 0

    (B) +1

    (C) +2

    (D) -1

  9. The coordination number of $Ni$ in $[Ni(C_2O_4)_3]^{4-}$ is: [BSEB, 2024 A]

    (A) 3

    (B) 6

    (C) 4

    (D) 5

  10. The oxidation state of $Fe$ in $[Fe(H_2O)_5NO]SO_4$ is: [BSEB, 2018 A]

    (A) +1

    (B) +2

    (C) +3

    (D) +4

  11. The oxidation number of $Fe$ in $K_4[Fe(CN)_6]$ is: [BSEB, 2019 A]

    (A) +2

    (B) +3

    (C) -2

    (D) -3

  12. The coordination number of $Cr$ in $K_3[Cr(C_2O_4)_3]$ is: [BSEB, 2021 A]

    (A) 3

    (B) 4

    (C) 5

    (D) 6

  13. An example of a complex having coordination number six (6) is: [BSEB, 2021 A]

    (A) $[Ni(CO)_4]^0$

    (B) $[Cu(NH_3)_4]SO_4$

    (C) $[Fe(CO)_5]^0$

    (D) $[Co(NH_3)_6]Cl_3$

  14. The coordination number of $Pt$ in $[Pt(NH_3)_6]^{4+}$ is: [BSEB, 2023 A]

    (A) 2

    (B) 4

    (C) 6

    (D) 8

  15. The coordination number of Iron (Fe) in $K_4[Fe(CN)_6]$ is: [BSEB, 2012 A]

    (A) 4

    (B) 6

    (C) 3

    (D) 2

  16. The coordination number of Cobalt in $[Co(en)_3]Cl_3$ is: [BSEB, 2017 A]

    (A) 3

    (B) 4

    (C) 6

    (D) 5

  17. The oxidation state of Cu in $[Cu(NH_3)_4]^{2+}$ is: [BSEB, 2018 A]

    (A) +1

    (B) +2

    (C) +3

    (D) 0

  18. The Effective Atomic Number (EAN) of Fe in $[Fe(CN)_6]^{3-}$ is: [BSEB, 2018 A]

    (A) 36

    (B) 35

    (C) 34

    (D) 37

  19. The oxidation state of Iron in $K_3[Fe(CN)_6]$ is: [BSEB, 2019 A]

    (A) +2

    (B) +3

    (C) +4

    (D) 0

  20. The coordination number of Fe in $[Fe(C_2O_4)_3]^{3-}$ is: [BSEB, 2021 A]

    (A) 3

    (B) 6

    (C) 4

    (D) 5

  21. The oxidation state of Cr in $[Cr(NH_3)_4Cl_2]Cl$ is: [BSEB, 2021 A]

    (A) +2

    (B) +3

    (C) +1

    (D) 0

  22. The coordination number of Cobalt in $[Co(NH_3)_5(CO_3)]Cl$ is: [BSEB, 2024 A]

    (A) 5

    (B) 6

    (C) 4

    (D) 7

  23. The coordination number of Ag in $[Ag(CN)_2]^-$ is: [BSEB, 2024 A]

    (A) 2

    (B) 4

    (C) 6

    (D) 1

  24. The oxidation number of Cobalt in $[Co(NH_3)_5Cl]^{2+}$ is: [BSEB, 2019 A]

    (A) +2

    (B) +3

    (C) +1

    (D) +4

  25. (2026) The oxidation state of Ni in $Ni(CO)_{4}$ is: [BSEB, 2026]

    (A) +4

    (B) +3

    (C) +2

    (D) 0

Topic 4: IUPAC Naming

  1. The IUPAC name of $[Ni(CO)_4]$ is: [BSEB, 2021 A]

    (A) Tetracarbonylnickellate (II)

    (B) Tetracarbonylnickel (II)

    (C) Tetracarbonylnickel (0)

    (D) Tetracarbonylnickel (O)

  2. The IUPAC name of $[Co(NH_3)_6]Cl_3$ is: [BSEB, 2025 A]

    (A) Hexaamminecobalt (III) chloride

    (B) Hexaamminecobalt (II) chloride

    (C) Hexaamminetrichloridocobalt (III)

    (D) None of these

  3. The IUPAC name of $K_3[Fe(CN)_6]$ is: [BSEB, 2024 A]

    (A) Potassium ferrocyanide

    (B) Potassium ferricyanide

    (C) Potassium hexacyanoferrate (II)

    (D) Potassium hexacyanoferrate (III)

  4. The IUPAC name of $H_2[PtCl_6]$ is: [BSEB, 2018 A]

    (A) Hydrogen hexachloroplatinic (IV) acid

    (B) Hydrogen hexachloroplatinate (II)

    (C) Hydrogen hexachloroido Pt (IV)

    (D) Hydrogen hexachloroido Pt (II)

  5. The molecular formula of Potassium hexacyanoferrate (II) is: [BSEB, 2012 A]

    (A) $K_3[Fe(CN)_6]$

    (B) $K_4[Fe(CN)_6]$

    (C) $K_2[Fe(CN)_6]$

    (D) $K[Fe(CN)_6]$

  6. The correct formula for Hexaammineplatinum (IV) chloride is: [BSEB, 2021 A]

    (A) $[Pt(NH_3)_6]Cl_4$

    (B) $[Pt(NH_3)_6]Cl_2$

    (C) $[Pt(NH_3)_2]Cl_3$

    (D) $[Pt(NH_3)_4]Cl_4$

  7. The IUPAC name of $[Ni(Cl)_4]^{2-}$ is: [BSEB, 2024 A]

    (A) Tetrachloronickel (II) ion

    (B) Tetrachloronickellate (0) ion

    (C) Tetrachloronickellate (II) ion

    (D) Nickel tetrachloride ion

  8. The IUPAC name of $K_2[Ni(CN)_4]$ is: [BSEB, 2021 A]

    (A) Potassium tetracyanonickel (II)

    (B) Potassium tetracyanonickellate (II)

    (C) Potassium tetracyanonickellate (0)

    (D) Tetracyanopotassium nickellate (II)

  9. The formula for Hexaaquamanganese (II) ion is: [BSEB, 2021 A]

    (A) $[Mn(H_2O)_6]^{2+}$

    (B) $[Mn(H_2O)_4]^{2+}$

    (C) $[Mn(H_2O)_6]^{3+}$

    (D) $[Mn(CN)_6]^{4-}$

  10. The name of $K_2[PtCl_6]$ is: [BSEB, 2012 A]

    (A) Potassium hexachloroplatinate (IV)

    (B) Potassium hexachloroplatinate (II)

    (C) Potassium chloroplatinate

    (D) None of these

  11. The correct IUPAC name of $[Cr(H_2O)_4Cl_2]Cl$ is: [BSEB, 2023 A]

    (A) Tetraaquadichloridochromium (III) chloride

    (B) Tetraaquadichloridochromium (II) chloride

    (C) Chloridochromium tetraaqua chloride

    (D) None of these

  12. The IUPAC name of $K_3[Al(C_2O_4)_3]$ is: [BSEB, 2021 A]

    (A) Potassium aluminate

    (B) Potassium trioxalatoaluminate (III)

    (C) Potassium aluminium oxalate

    (D) Aluminium potassium oxalate

  13. The name of $[Pt(NH_3)_2Cl_2]$ is: [BSEB, 2016 A]

    (A) Diamminedichloridoplatinum (II)

    (B) Diamminedichloridoplatinum (IV)

    (C) Dichloroplatinum diammine

    (D) None of these

Topic 5: Isomerism

  1. How many geometrical isomers are possible for $[Pt(NH_3)_2Cl_2]$? [BSEB, 2024 A]

    (A) 2

    (B) 3

    (C) 4

    (D) 0

  2. $[Co(NH_3)_5Br]SO_4$ and $[Co(NH_3)_5SO_4]Br$ are which type of isomers? [BSEB, 2022 A]

    (A) Ionization isomers

    (B) Linkage isomers

    (C) Coordination isomers

    (D) Geometrical isomers

  3. Which of the following cannot show linkage isomerism? [BSEB, 2025 A]

    (A) $NO_2^-$

    (B) $SCN^-$

    (C) $CN^-$

    (D) $NH_3$

  4. How many geometrical isomers of the complex $[Co(NH_3)_4Cl_2]Cl$ are possible? [BSEB, 2015 A]

    (A) 2

    (B) 3

    (C) 4

    (D) 1

  5. How many possible isomers are there for the complex compound $[Co(C_2O_4)_2(NH_3)_2]$? [BSEB, 2011 A]

    (A) 1

    (B) 2

    (C) 3

    (D) 4

  6. The complex ion which shows coordination isomerism is: [BSEB, 2020 A]

    (A) $[Co(NH_3)_6][Cr(CN)_6]$

    (B) $[Co(NH_3)_5Cl]Cl_2$

    (C) $[Pt(NH_3)_2Cl_2]$

    (D) $[Ni(CO)_4]$

  7. How many ionization isomers are possible for $[Co(NH_3)_4Cl_2]Cl$? [BSEB, 2022 A]

    (A) 2

    (B) 1

    (C) 3

    (D) 4

  8. Which of the following shows optical isomerism? [BSEB, 2018 A]

    (A) $[Co(en)_3]^{3+}$

    (B) $[Zn(en)_2]^{2+}$

    (C) $[Co(NH_3)_6]^{3+}$

    (D) $[Cu(NH_3)_4]^{2+}$

  9. The number of geometrical isomers of the complex ion $[Cr(C_2O_4)_2(H_2O)_2]^-$ is: [BSEB, 2021 A]

    (A) 2

    (B) 3

    (C) 4

    (D) 1

  10. (2026) $[Co(NH_{3})_{5}Br]SO_{4}$ and $[Co(NH_{3})_{5}SO_{4}]Br$ are related as: [BSEB, 2026]

    (A) Ionization isomers

    (B) Linkage isomers

    (C) Coordination isomers

    (D) Geometrical isomers

Topic 6: Bonding (VBT & CFT)

  1. The geometry of $[Ni(CO)_4]$ is: [BSEB, 2009 A]

    (A) Tetrahedral

    (B) Square-planar

    (C) Octahedral

    (D) None of these

  2. The hybridization of $Fe$ in $K_4[Fe(CN)_6]$ is: [BSEB, 2011 A]

    (A) $dsp^2$

    (B) $sp^3$

    (C) $d^2sp^3$

    (D) $sp^3d^2$

  3. The shape of the complex ion $[Ni(CN)_4]^{2-}$ is: [BSEB, 2025 A]

    (A) Linear

    (B) Tetrahedral

    (C) Square planar

    (D) Octahedral

  4. The hybridization of the central metal in which compound is $dsp^2$? [BSEB, 2018 C]

    (A) $[Fe(CO)_5]$

    (B) $[Ni(CO)_4]$

    (C) $[Ni(CN)_4]^{2-}$

    (D) $[Cr(H_2O)_6]^{3+}$

  5. What is the hybridization of Nickel in $[Ni(CN)_4]^{2-}$? [BSEB, 2019 A]

    (A) $sp^3$

    (B) $dsp^2$

    (C) $d^2sp^3$

    (D) $sp^3d^2$

  6. What is the hybridization of $Fe$ in $K_3[Fe(CN)_6]$? [BSEB, 2015 A]

    (A) $sp^3$

    (B) $dsp^2$

    (C) $d^2sp^3$

    (D) $sp^3d^2$

  7. The geometry of complex ion $[Cu(NH_3)_4]^{2+}$ is square planar, then hybridization of $Cu^{2+}$ is: [BSEB, 2016 A]

    (A) $sp^3$

    (B) $sp^3d^2$

    (C) $dsp^2$

    (D) $dsp^3$

  8. The structure of $[NiCl_4]^{2-}$ is: [BSEB, 2012 A]

    (A) Square planar

    (B) Tetrahedral

    (C) Octahedral

    (D) Linear

  9. Which of the following has tetrahedral shape: [BSEB, 2012 A, 2018 A]

    (A) $[Ni(CN)_4]^{2-}$

    (B) $[Pd(CN)_4]^{2-}$

    (C) $[PdCl_4]^{2-}$

    (D) $[NiCl_4]^{2-}$

  10. Which of the following is an inner orbital complex ion? [BSEB, 2021 A]

    (A) $[Fe(CN)_6]^{4-}$

    (B) $[Fe(NH_3)_6]^{3+}$

    (C) $[FeF_6]^{3-}$

    (D) None of these

  11. The geometry of $[Ag(NH_3)_2]^+$ ion is: [BSEB, 2016 A]

    (A) Linear

    (B) Square planar

    (C) Tetrahedral

    (D) Octahedral

  12. Which of the following complexes is an outer orbital complex? [BSEB, 2024 A]

    (A) $[Fe(CN)_6]^{3-}$

    (B) $[Co(NH_3)_6]^{3+}$

    (C) $[CoF_6]^{3-}$

    (D) $[Mn(CN)_6]^{3-}$

  13. The geometry of $[Ni(NH_3)_6]^{2+}$ is: [BSEB, 2021 A]

    (A) Tetrahedral

    (B) Square planar

    (C) Octahedral

    (D) Linear

  14. The hybridization of Mn in $[Mn(CN)_6]^{4-}$ is: [BSEB, 2021 A]

    (A) $sp^3d^2$

    (B) $d^2sp^3$

    (C) $dsp^2$

    (D) $sp^3$

  15. The geometry having $dsp^2$ hybridization is: [BSEB, 2020 A]

    (A) Tetrahedral

    (B) Square planar

    (C) Octahedral

    (D) Trigonal bipyramidal

  16. According to CFT, the splitting of $d$-orbitals for octahedral complexes occurs in which two groups? [BSEB, 2020 A]

    (A) $t_{2g}$ and $e_g$

    (B) $s$ and $p$

    (C) $d_{xy}$ and $d_{yz}$

    (D) None of these

  17. The value of $\Delta_0$ (Octahedral crystal field splitting energy) will be maximum for: [BSEB, 2022 A]

    (A) For $F^-$

    (B) For $Cl^-$

    (C) For $CN^-$

    (D) For $H_2O$

  18. The $\Delta_0$ of which of the following ligands is minimum? [BSEB, 2021 A]

    (A) $CO$

    (B) $NH_3$

    (C) $CN^-$

    (D) $F^-$

Topic 7: Magnetic Properties & Color

  1. Which of the following is paramagnetic? [BSEB, 2022 A]

    (A) $Ni(CO)_4$

    (B) $[Ni(CN)_4]^{2-}$

    (C) $[NiCl_4]^{2-}$

    (D) $[Co(NH_3)_6]^{3+}$

  2. Which of the following ions is colorless? [BSEB, 2021 A]

    (A) $Cu^{2+}$

    (B) $Ti^{3+}$

    (C) $V^{3+}$

    (D) $Sc^{3+}$

  3. Which of the following complex compounds has the highest paramagnetic moment? [BSEB, 2018 A]

    (A) $[Cr(H_2O)_6]^{3+}$

    (B) $[Fe(H_2O)_6]Cl_2$

    (C) $[Fe(CN)_6]^{4-}$

    (D) $[Ni(CO)_4]$

  4. What is the color of coordination compound $[Cu(NH_3)_4]^{2+}$? [BSEB, 2018 A]

    (A) Blue

    (B) Red

    (C) Green

    (D) Yellow

  5. The number of unpaired electrons in hexacyanoferrate (III) ion $[Fe(CN)_6]^{3-}$ is: [BSEB, 2021 A]

    (A) 0

    (B) 1

    (C) 2

    (D) 3

  6. The nature of $[Co(NH_3)_6]^{3+}$ ion is: [BSEB, 2022 A]

    (A) Paramagnetic

    (B) Diamagnetic

    (C) Ferromagnetic

    (D) None of these

  7. Which of the following ions is diamagnetic? [BSEB, 2015 A]

    (A) $[Fe(H_2O)_6]^{2+}$

    (B) $[CoF_6]^{3-}$

    (C) $[Ni(CN)_4]^{2-}$

    (D) $[Cu(H_2O)_6]^{2+}$

  8. The magnetic behavior of $[Ni(CN)_4]^{2-}$ ion is: [BSEB, 2022 A]

    (A) Paramagnetic

    (B) Diamagnetic

    (C) Ferromagnetic

    (D) None of these

  9. What is the color of $[Fe(CN)_6]^{4-}$? [BSEB, 2019 C]

    (A) Pale yellow

    (B) Dark blue

    (C) Red

    (D) Green

  10. The number of unpaired electrons in $[NiCl_4]^{2-}$ is: [BSEB, 2021 A]

    (A) 0

    (B) 2

    (C) 4

    (D) 3

  11. The magnetic moment of $[Fe(H_2O)_6]^{2+}$ is approximately: [BSEB, 2024 A]

    (A) 1.73 BM

    (B) 2.83 BM

    (C) 4.90 BM

    (D) 5.92 BM

Topic 8: Stability & Theories

  1. Which of the following is most stable? [BSEB, 2021 A]

    (A) $[Fe(H_2O)_6]^{3+}$

    (B) $[Fe(CN)_6]^{4-}$

    (C) $[Fe(CN)_6]^{3+}$

    (D) $[Fe(C_2O_4)_3]^{3-}$

  2. Who gave the most important theory for coordination compounds? [BSEB, 2023 A]

    (A) Slater

    (B) Pauling

    (C) Werner

    (D) Lewis

  3. According to Werner’s theory, secondary valency of metals is: [BSEB, 2018 A]

    (A) Ionizable

    (B) Non-ionizable

    (C) Variable

    (D) None of these

  4. Which of the following does not follow the Effective Atomic Number (EAN) rule? [BSEB, 2023 A]

    (A) $Fe(CO)_5$

    (B) $[Ni(CO)_4]$

    (C) $[Cu(NH_3)_4]^{2+}$

    (D) $K_4[Fe(CN)_6]$

  5. The primary valency of metals in coordination compounds is: [BSEB, 2020 A]

    (A) Ionizable

    (B) Non-ionizable

    (C) Coordination

    (D) Fixed

  6. According to Werner’s theory of coordination compounds, secondary valency represents: [BSEB, 2018 C]

    (A) Oxidation state

    (B) Coordination number

    (C) Charge

    (D) Magnetic moment

  7. Which of the following ions will form the most stable complex? [BSEB, 2021 A]

    (A) $Cu^{2+}$

    (B) $Ni^{2+}$

    (C) $Fe^{2+}$

    (D) $CO^{2+}$

Topic 9: Biological Importance & Applications

  1. The main metal ion present in chlorophyll is: [BSEB, 2016 A, 2023 A]

    (A) $Fe^{2+}$

    (B) $Mg^{2+}$

    (C) $Co^{2+}$

    (D) $Zn^{2+}$

  2. Vitamin $B_{12}$ contains: [BSEB, 2024 A]

    (A) Cobalt

    (B) Magnesium

    (C) Iron

    (D) Nickel

  3. The transition metal which is used as a Ziegler-Natta catalyst is: [BSEB, 2019 C]

    (A) $Ti$

    (B) $Th$

    (C) $Tl$

    (D) $Te$

  4. The complex used in the treatment of cancer is: [BSEB, 2024 A]

    (A) $[Pt(NH_3)_4]Cl_2$

    (B) Cis-platin $[Pt(NH_3)_2Cl_2]$

    (C) Trans-platin

    (D) $K_2[PtCl_4]$

  5. The metal present in hemoglobin is: [BSEB, 2015 A]

    (A) Iron (Fe)

    (B) Magnesium (Mg)

    (C) Cobalt (Co)

    (D) Zinc (Zn)

  6. The metal used in Wilkinson’s Catalyst is: [BSEB, 2020 A]

    (A) $Pt$

    (B) $Pd$

    (C) $Rh$ (Rhodium)

    (D) $Ir$

  7. What is $K_2[HgI_4]$ called? [BSEB, 2018 C]

    (A) Tollen’s reagent

    (B) Nessler’s reagent

    (C) Benedict’s solution

    (D) Fehling’s solution

  8. Which complex ion is formed in the extraction of silver? [BSEB, 2023 A]

    (A) $[Ag(CN)_2]^-$

    (B) $[Ag(NH_3)_2]^+$

    (C) $[AgCl_2]^-$

    (D) $[Ag(S_2O_3)_2]^{3-}$

  9. (2026) Vitamin $B_{12}$ contains: [BSEB, 2026]

    (A) Cobalt

    (B) Magnesium

    (C) Iron

    (D) Nickel

Topic 10: Complexes & Reactions

  1. The oxidation state of Ni in $Ni(CO)_4$ is: [BSEB, 2026]

    (A) +4

    (B) +3

    (C) +2

    (D) 0

  2. The number of ions in the aqueous solution of $[Co(NH_3)_5Cl]Cl_2$ will be: [BSEB, 2021 A]

    (A) 3

    (B) 4

    (C) 2

    (D) 6

  3. Which will give a white precipitate with $AgNO_3$ in aqueous solution? [BSEB, 2019 A]

    (A) $[Co(NH_3)_6]Cl_3$

    (B) $[Co(NH_3)_5Cl]Cl_2$

    (C) $[Co(NH_3)_4Cl_2]Cl$

    (D) All of these

  4. The formula of Sodium nitroprusside is: [BSEB, 2017 A]

    (A) $Na_2[Fe(CN)_5NO]$

    (B) $Na_3[Fe(CN)_6]$

    (C) $Na_4[Fe(CN)_6]$

    (D) None of these

  5. Reagent which is used for the identification of $Cu^{2+}$ ion: [BSEB, 2019 C]

    (A) $NH_3$

    (B) $K_4[Fe(CN)_6]$

    (C) $NaOH$

    (D) $H_2S$

  6. Potash alum is an example of: [BSEB, 2011 A]

    (A) Salt

    (B) Simple salt

    (C) Double salt

    (D) Complex salt

  7. What type of complex compound is $[Co(NH_3)_6]Cl_3$? [BSEB, 2017 C]

    (A) Cationic complex compound

    (B) Anionic complex compound

    (C) Neutral complex compound

    (D) None of these

  8. Which of the following compounds is used in fire extinguishers? [BSEB, 2022 A]

    (A) $CCl_4$

    (B) $CHCl_3$

    (C) $CH_3Cl$

    (D) $COCl_2$

  9. Which of the following has the highest molar conductivity in aqueous solution? [BSEB, 2024 A]

    (A) $[Pt(NH_3)_6]Cl_4$

    (B) $[Pt(NH_3)_5Cl]Cl_3$

    (C) $[Pt(NH_3)_4Cl_2]Cl_2$

    (D) $[Pt(NH_3)_3Cl_3]Cl$

  10. In which of the following is Synergic Bonding found? [BSEB, 2021 A]

    (A) Metal carbonyls

    (B) Metal ammine complexes

    (C) Hydrated salts

    (D) None of these

Syllabus-based Remaining MCQs

  1. Complexes are: [BSEB, 2015 A]

    (A) Of one type

    (B) Of two types

    (C) Of three types

    (D) Of four types

  2. The complex ion in which the central metal atom has no $d$-electron: [BSEB, 2022 A]

    (A) $[MnO_4]^-$

    (B) $[Co(NH_3)_6]^{3+}$

    (C) $[Fe(CN)_6]^{3-}$

    (D) $[Cr(H_2O)_6]^{3+}$

  3. Green vitriol is: [BSEB, 2015 A]

    (A) $FeSO_4 \cdot 7H_2O$

    (B) $CuSO_4 \cdot 5H_2O$

    (C) $CaSO_4 \cdot 2H_2O$

    (D) None of these

  4. What will be the effective atomic number of cobalt in $[Co(en)_2Cl_2]^\oplus$ complex ion? [BSEB, 2017 A]

    (A) 27

    (B) 36

    (C) 33

    (D) 35

  5. The effective atomic number of $Co$ in complex ion $[Co(en)_2Cl_2]^+$ is: [BSEB, 2025 A]

    (A) 27

    (B) 36

    (C) 33

    (D) 35

  6. $K_4[Fe(CN)_6]$ is an example of: [BSEB, 2015 A]

    (A) Ionic complex

    (B) Molecular complex

    (C) Bridge complex

    (D) Different from these

  7. The main use of T.E.L. (Tetra Ethyl Lead) is: [BSEB, 2017 C]

    (A) As a polymer

    (B) As an anti-knock compound

    (C) As a heat insulator

    (D) As a solvent

  8. The coordination number of sodium in $Na_2O$ is: [BSEB, 2015 A]

    (A) 6

    (B) 4

    (C) 8

    (D) 2

  9. Which of the following is an inner orbital complex? [BSEB, 2025 A]

    (A) $[Co(NH_3)_6]^{3+}$

    (B) $[Ni(NH_3)_6]^{2+}$

    (C) $[Zn(NH_3)_6]^{2+}$

    (D) $[FeF_6]^{3-}$

  10. The number of ions in the solution of complex compound $[Co(NH_3)_5Cl]Cl_2$ is: [BSEB, 2026]

    (A) 3

    (B) 4

    (C) 2

    (D) 6

  11. $[Co(NH_3)_5Br]SO_4$ and $[Co(NH_3)_5SO_4]Br$ are related to each other as: [BSEB, 2026]

    (A) Ionization isomers

    (B) Linkage isomers

    (C) Coordination isomers

    (D) Geometrical isomers

  12. Vitamin $B_{12}$ contains: [BSEB, 2026]

    (A) Cobalt

    (B) Magnesium

    (C) Iron

    (D) Nickel

  13. The oxidation state of Ni in $Ni(CO)_4$ is: [BSEB, 2026]

    (A) +4

    (B) +3

    (C) +2

    (D) 0

  14. The number of ions in the aqueous solution of $[Co(NH_3)_5Cl]Cl_2$ is: [BSEB, 2026]

    (A) 3

    (B) 4

    (C) 2

    (D) 6

  15. $[Co(NH_3)_5Br]SO_4$ and $[Co(NH_3)_5SO_4]Br$ are related to each other in what way? [BSEB, 2026]

    (A) Ionization isomers

    (B) Linkage isomers

    (C) Coordination isomers

    (D) Geometrical isomers

  16. How many ions are obtained in the aqueous solution of $K_4[Fe(CN)_6]$? [BSEB, 2019 A]

    (A) 4

    (B) 5

    (C) 3

    (D) 1

  17. What is the hybridization of $Fe$ in $[Fe(CN)_6]^{4-}$? [BSEB, 2011 A]

    (A) $dsp^2$

    (B) $sp^3$

    (C) $d^2sp^3$

    (D) $sp^3d^2$

  18. Potash alum is an example of: [BSEB, 2011 A]

    (A) Salt

    (B) Simple salt

    (C) Double salt

    (D) Complex salt

  19. The IUPAC name of $[Co(NH_3)_6]Cl_3$ is: [BSEB, 2025 A]

    (A) Hexaamminecobalt (III) chloride

    (B) Hexaamminecobalt (II) chloride

    (C) Hexaamminetrichloridocobalt (III)

    (D) None of these

  20. The main element present in Vitamin $B_{12}$ is: [BSEB, 2024 A]

    (A) Cobalt

    (B) Magnesium

    (C) Iron

    (D) Nickel

Bihar Board Class 12th के (Chemistry/रसायन विज्ञानं ) = रसायन विज्ञानं ‘भाग-1 (Englsih Medium) Book Chapter-9 Coordination Compounds के Exam 2027 MCQs Questions Answer Key

Q. No.AnswerQ. No.AnswerQ. No.AnswerQ. No.Answer
1(D)39(B)77(B)115(B)
2(B)40(C)78(C)116(A)
3(C)41(B)79(C)117(C)
4(B)42(B)80(B)118(B)
5(D)43(B)81(D)119(A)
6(A)44(B)82(A)120(A)
7(B)45(B)83(A)121(D)
8(B)46(B)84(C)122(A)
9(C)47(A)85(C)123(D)
10(B)48(B)86(B)124(A)
11(B)49(D)87(B)125(B)
12(B)50(C)88(A)126(C)
13(A)51(A)89(C)127(A)
14(B)52(D)90(D)128(A)
15(B)53(A)91(C)129(A)
16(A)54(B)92(D)130(A)
17(C)55(A)93(B)131(C)
18(C)56(C)94(A)132(A)
19(C)57(B)95(B)133(A)
20(A)58(A)96(B)134(B)
21(C)59(A)97(C)135(B)
22(C)60(A)98(A)136(A)
23(B)61(B)99(B)137(B)
24(B)62(A)100(C)138(B)
25(A)63(2)101(B)139(A)
26(C)64(A)102(A)140(A)
27(A)65(D)103(B)141(A)
28(C)66(A)104(C)142(A)
29(D)67(C)105(D)143(D)
30(B)68(A)106(C)144(A)
31(B)69(A)107(B)145(A)
32(A)70(A)108(C)146(B)
33(B)71(A)109(A)147(C)
34(A)72(A)110(B)148(C)
35(A)73(A)111(A)149(A)
36(D)74(C)112(B)150(A)
37(D)75(C)113(A)
38(C)76(C)114(A)

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